Unusual solvent polarity dependent excitation relaxation dynamics of a bis[p-ethynyldithiobenzoato]Pd-linked bis[(porphinato)zinc] complex

Author:

Park Jaehong12345ORCID,Park Tae-Hong678910,Sinks Louise E.6789,Deria Pravas67896ORCID,Park Jiyong611121314ORCID,Baik Mu-Hyun611121314ORCID,Therien Michael J.61516179ORCID

Affiliation:

1. Department of Molecular Engineering

2. Graduate School of Engineering

3. Kyoto University

4. Kyoto

5. Japan

6. Department of Chemistry

7. University of Pennsylvania

8. Philadelphia

9. USA

10. Nuclear Chemistry Research Division

11. Korea Advanced Institute of Science and Technology (KAIST) & Center for Catalytic Hydrocarbon Functionalizations

12. Institute for Basic Science (IBS)

13. Daejeon 34141

14. South Korea

15. Duke University

16. French Family Science Center

17. Durham

Abstract

A porphyrin dimer linked by a Pd(ii)-based linker displays unusual excited-state dynamics where solvent polarity steers singlet and triplet decay-channel population.

Funder

National Research Foundation of Korea

Basic Energy Sciences

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Process Chemistry and Technology,Energy Engineering and Power Technology,Biomedical Engineering,Chemical Engineering (miscellaneous),Chemistry (miscellaneous)

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