Shear-aligned large-area organic semiconductor crystals through extended π–π interaction

Author:

Zhang Song1ORCID,Talnack Felix2ORCID,Jousselin-Oba Tanguy3,Bhat Vinayak4ORCID,Wu Yilei1ORCID,Lei Yusheng15ORCID,Tomo Yoko16ORCID,Gong Huaxin1ORCID,Michalek Lukas1ORCID,Zhong Donglai1ORCID,Wu Can1ORCID,Yassar Abderrahim7ORCID,Mannsfeld Stefan2ORCID,Risko Chad4ORCID,Frigoli Michel3ORCID,Bao Zhenan1

Affiliation:

1. Department of Chemical Engineering, Stanford University, Stanford, California, 94305, USA

2. Center for Advancing Electronics Dresden (cfaed), Technische Universität Dresden, Dresden, 01062, Germany

3. Institut Lavoisier de Versailles, UMR CNRS 8180, University Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France

4. Department of Chemistry and Center for Applied Energy Research, University of Kentucky, Lexington, Kentucky 40506, USA

5. Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception, Institute of Optoelectronics, Fudan University, Shanghai 200433, China

6. Department of Mechanical Engineering, Kyushu University, 744 Mottoka Nishi-ku, Fukuoka, 819-0395, Japan

7. LPICM, UMR CNRS 7647, Ecole Polytechnique, 91128 Palaiseau Cedex, France

Abstract

TIPS-PPP, a novel TIPS-PEN derivative, features a vertically extended pentacene core for increased π–π overlap, enabling exploration of structure–morphology–property connections and exhibiting enhanced stability/electronic performance.

Funder

Deutsche Forschungsgemeinschaft

Agence Nationale de la Recherche

Office of Naval Research

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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