A facile and convenient sequential homobimetallic catalytic approach towards β-methylstyrenes. A one-pot Stille cross-coupling/isomerization strategy-Reference-Cited by-同舟云学术

A facile and convenient sequential homobimetallic catalytic approach towards β-methylstyrenes. A one-pot Stille cross-coupling/isomerization strategy

Published:2014 Issue:22 Volume:12 Page:3735-3743
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Simonetti Sebastián O.¹²³⁴,Larghi Enrique L.¹²³⁴,Kaufman Teodoro S.¹²³⁴

Affiliation:

1. Instituto de Química Rosario (IQUIR

2. CONICET-UNR) and Facultad de Ciencias Bioquímicas y Farmacéuticas

3. Universidad Nacional de Rosario

4. S2002LRK Rosario, Argentina

Abstract

A one-pot approach towards β-methylstyrenes is reported. The transformation involves a Stille cross-coupling reaction of aryl halides with allyltributylstannane, followed by an in situ Pd-catalyzed double bond conjugative migration.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00604F

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