Characterization of a Rh(iii) porphyrin–CO complex: its structure and reactivity with an electron acceptor
Author:
Affiliation:
1. Research Institute of Electrochemical Energy
2. Department of Energy and Environment
3. National Institute of Advanced Industrial Science and Technology (AIST)
4. Ikeda
5. Japan
6. Rigaku Corporation
7. Akishima
Abstract
To analyse the electrocatalytic oxidation of carbon monoxide by Rh porphyrins, we isolated a CO-adduct of Rh octaethylporphyrin, and examined its properties and reactivity by IR, NMR, and X-ray crystallographic analyses.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01453K
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