Theoretical insight into the origin of the electrochemical promotion of ethylene oxidation on ruthenium oxide-Reference-Cited by-同舟云学术

Theoretical insight into the origin of the electrochemical promotion of ethylene oxidation on ruthenium oxide

Published:2019 Issue:21 Volume:9 Page:5915-5926
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Hajar Yasmine M.¹²³⁴⁵^ORCID,Treps Laureline⁶⁷⁸⁹¹⁰,Michel Carine⁶⁷⁸⁹¹⁰^ORCID,Baranova Elena A.¹²³⁴⁵^ORCID,Steinmann Stephan N.⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering

2. Centre for Catalysis Research and Innovation (CCRI)

3. University of Ottawa

4. Ottawa

5. Canada

6. Univ. Lyon

7. ENS de Lyon

8. CNRS

9. Université Lyon 1

10. Laboratoire de Chimie UMR 5182

Abstract

In EPOC the adsorption energies of the reactants and products are modified by applying an electrochemical potential to the catalyst. DFT computations unveil that the C–C and O–O bond dissociation are accelerated under positive and negative potential, respectively.

Funder

Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CY/C9CY01421G

Reference82 articles.

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3. The effect of electrochemical oxygen pumping on the rate and selectivity of ethylene oxidation on polycrystalline silver

4. Non-Faradaic electrochemical modification of catalytic activity

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