A thermally remendable and reprocessable crosslinked methyl methacrylate polymer based on oxygen insensitive dynamic reversible C–ON bonds
Author:
Affiliation:
1. Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education
2. GD HPPC Lab School of Chemistry and Chemical Engineering
3. Sun Yat-sen University
4. Guangzhou 510275
5. P. R. China
6. Materials Science Institute
Abstract
A strategy for developing self-healing crosslinked polymer with alkoxyamine is proposed, which ensures air resistance even at higher homolysis temperature.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA22275C
Reference29 articles.
1. M. Q. Zhang and M. Z.Rong, Self-healing Polymers and Polymer Composites, John Wiley & Sons, Inc., Hoboken, 2011
2. Intrinsic self-healing of covalent polymers through bond reconnection towards strength restoration
3. Olefin Metathesis for Effective Polymer Healing via Dynamic Exchange of Strong Carbon–Carbon Double Bonds
4. Dynamic Hydrogels with an Environmental Adaptive Self-Healing Ability and Dual Responsive Sol–Gel Transitions
5. Room-Temperature Self-Healable and Remoldable Cross-linked Polymer Based on the Dynamic Exchange of Disulfide Bonds
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