Co(<scp>ii/iii</scp>), Ni(<scp>ii</scp>) and Cu(<scp>ii</scp>) complexes with a pyrazole-functionalized 1,3,5-triazopentadiene: synthesis, structure and application in the oxidation of styrene to benzaldehyde-Reference-Cited by-同舟云学术

Co(ii/iii), Ni(ii) and Cu(ii) complexes with a pyrazole-functionalized 1,3,5-triazopentadiene: synthesis, structure and application in the oxidation of styrene to benzaldehyde

Published:2023 Issue:22 Volume:47 Page:10826-10833
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mahmudov Ibadulla¹²,Gurbanov Atash V.¹³,Martins Luísa M. D. R. S.¹,Abdullayev Yusif⁴⁵,Sujayev Afsun²,Mahmudov Kamran T.¹³^ORCID,Pombeiro Armando J. L.¹^ORCID

Affiliation:

1. Centro de Química Estrutural, Institute of Molecular Sciences, and Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, Lisboa 1049-001, Portugal

2. Institute of Chemistry of Additives, Azerbaijan National Academy of Sciences, Baku Az 1029, Azerbaijan

3. Excellence Center, Baku State University, Z. Xalilov Str. 23, Baku Az 1148, Azerbaijan

4. Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, Baku AZ 1025, Azerbaijan

5. Department of Chemical Engineering, Baku Engineering University, Hasan Aliyev str. 120, Absheron, Baku, AZ 0101, Azerbaijan

Abstract

The synthesis, supramolecular packing and intermolecular interactions of Co(ii/iii), Ni(ii) and Cu(ii) carbamimidoyl (imino(1H-pyrazol-1-yl)methyl)amidates are reported, as well as their catalytic activity in the oxidation of styrene to benzaldehyde.

Funder

Fundação para a Ciência e a Tecnologia

Instituto Superior Técnico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ01120H

Reference42 articles.

1. The Chemistry of β-Diketiminatometal Complexes

2. β-Diketiminate complexes of the first row transition metals: applications in catalysis