Visible-light-driven 1,2-hydro(cyanomethylation) of alkenes with chloroacetonitrile
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Published:2023
Issue:43
Volume:21
Page:8642-8645
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ISSN:1477-0520
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Container-title:Organic & Biomolecular Chemistry
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language:en
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Short-container-title:Org. Biomol. Chem.
Author:
Fuke Keito1,
Miura Tomoya1ORCID
Affiliation:
1. Division of Applied Chemistry, Okayama University, Tsushimanaka, Okayama 700-8530, Japan
Abstract
One-carbon-extended nitriles are synthesized by a visible-light-driven 1,2-hydro(cyanomethylation) of alkenes with chloroacetonitrile. A cyanomethyl radical adds onto alkenes to form an alkyl radical, which undergoes hydrogen atom transfer from thiol.
Funder
Japan Society for the Promotion of Science
Sumitomo Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference40 articles.
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