The central role of the metal ion for photoactivity: Zn– vs. Ni

The central role of the metal ion for photoactivity: Zn– vs. Ni–Mabiq

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lauenstein Raphael¹²³,Mader Sophie L.⁴²³^ORCID,Derondeau Henrieta⁵⁶⁷⁸³^ORCID,Esezobor Oaikhena Z.¹²³,Block Matthias⁵⁶⁷⁸³,Römer Armin J.⁴²³,Jandl Christian¹²³,Riedle Eberhard⁵⁶⁷⁸³^ORCID,Kaila Ville R. I.⁴²³^ORCID,Hauer Jürgen¹²³,Thyrhaug Erling¹²³^ORCID,Hess Corinna R.¹²³^ORCID

Affiliation:

1. Department of Chemistry and Catalysis Research Center

2. Technical University of Munich

3. Germany

4. Department of Chemistry

5. Lehrstuhl für BioMolekulare Optik

6. Fakultät für Physik

7. Ludwig-Maximilians-Universität München

8. 80538 Munich

Abstract

The development of earth-abundant photoredox catalysts remains a challenge. Studies of Ni- and Zn-Mabiq complexes demonstrate how the coordinating metal ion influences the photochemistry, photodynamics and reactivity of photocatalysts.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06096H

Reference55 articles.

1. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

2. Photoredox Catalysis in Organic Chemistry

3. Solar Synthesis: Prospects in Visible Light Photocatalysis