Heteroleptic cobalt(iii) acetylacetonato complexes with N-heterocyclic carbine-donating scorpionate ligands: synthesis, structural characterization and catalysis

Author:

Nishiura Toshiki12345,Takabatake Asako12345,Okutsu Mariko12345,Nakazawa Jun12345ORCID,Hikichi Shiro12345ORCID

Affiliation:

1. Department of Material and Life Chemistry

2. Faculty of Engineering

3. Kanagawa University

4. Yokohama 221-8686

5. Japan

Abstract

A first structure-determined heteroleptic cobalt(iii) complex with the less hindered tris(carbene)borate works as a catalyst precursor for alkane oxidation.

Funder

Core Research for Evolutional Science and Technology

Kanagawa University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference43 articles.

1. N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools: Edition 2 (RSC Catalysis Series No.27) , ed. S. Diez-Gonzalez , The Royal Society of Chemistry , London , 2017

2. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis (Catalysis by Metal Complexes, vol.32) , ed. C. S. J. Cazin , Springer Science+Business Media , Berlin , 2011

3. N-Heterocyclic Carbenes in Transition Metal Catalysis (Topics in Organometallic Chemistry, vol.21) , ed. F. Glorius , Springer-Verlag , Berlin, Heidelberg , 2007

4. Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis

5. Boron‐Centered Scorpionate‐Type NHC‐Based Ligands and Their Metal Complexes

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