Disentangling the complex photodynamics of mixed-linker Zr-MOFs – efficient energy and charge transfer processes

Author:

Gutiérrez Mario1ORCID,Di Nunzio Maria Rosaria1ORCID,Caballero-Mancebo Elena1,Sánchez Félix2ORCID,Cohen Boiko1ORCID,Douhal Abderrazzak1ORCID

Affiliation:

1. Departamento de Química Física, Facultad de Ciencias Ambientales y Bioquímica, INAMOL, Universidad de Castilla-La Mancha, Avenida Carlos III, S. N., 45071, Toledo, Spain

2. Instituto de Química Orgánica, CSIC, Juan de la Cierva, 3, 28006, Madrid, Spain

Abstract

Photodynamics of two mixed-linker Zr-MOFs showing different relaxation pathways including energy transfer, ligand-to-metal charge transfer, and long-lived charge separated states, which depends on the used modulators in the synthesis of the MOFs.

Funder

Ministerio de Ciencia e Innovación

Universidad de Castilla-La Mancha

Junta de Comunidades de Castilla-La Mancha

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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