Cyclometalated titanium and zirconium complexes stabilised by a new silylmethylene-linked tetradentate triamidophosphine-Reference-Cited by-同舟云学术

Cyclometalated titanium and zirconium complexes stabilised by a new silylmethylene-linked tetradentate triamidophosphine

Published:2016 Issue:7 Volume:45 Page:3013-3023
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sietzen M.¹²³⁴,Federmann P.¹²³⁴,Sonnenschein C.¹²³⁴,Wadepohl H.¹²³⁴,Ballmann J.¹²³⁴^ORCID

Affiliation:

1. Anorganisch-Chemisches Institut

2. Ruprecht-Karls-Universität Heidelberg

3. 69120 Heidelberg

4. Germany

Abstract

Reactive titanium and zirconium alkyl species coordinated by a new tetradentateN-phenyl substituted silylmethylene-linked triamidophosphine ligand were shown to undergo cyclometalation at theortho-N-phenyl positons affording titana- and zirconazetidines.

Funder

Verband der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04561D

Reference90 articles.

1. Atranes: new examples with unexpected properties

2. A novel transmetalation reaction: a route to transition metallatranes