A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate-Reference-Cited by-同舟云学术

A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate

Published:2019 Issue:23 Volume:7 Page:14019-14026
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Gunasekar Gunniya Hariyanandam¹²³⁴^ORCID,Yoon Sungho⁵⁶⁷⁴^ORCID

Affiliation:

1. Clean Energy Research Centre

2. Korea Institute of Science and Technology

3. Cheongryang

4. Republic of Korea

5. Department of Applied Chemistry

6. Kookmin University

7. Seongbuk-gu

Abstract

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl₃ afforded a single-site, highly active and selective catalyst for the hydrogenation of CO₂ to formate.

Funder

Ministry of Science, ICT and Future Planning

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/TA/C9TA03807H

Reference79 articles.

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2. Chemistry of Covalent Organic Frameworks

3. Design and synthesis of porous polymeric materials and their applications in gas capture and storage: a review