Femtosecond predissociation dynamics of the methyl radical from the 3pz Rydberg state

Author:

Balerdi Garikoitz12345,Woodhouse Joanne12345,Zanchet Alexander6785,de Nalda Rebeca9785,Senent María L.10117125,García-Vela Alberto6785,Bañares Luis12345

Affiliation:

1. Departamento de Química Física

2. Facultad de Ciencias Químicas

3. Universidad Complutense de Madrid (Unidad Asociada I+D+i CSIC)

4. 28040 Madrid

5. Spain

6. Instituto de Física Fundamental

7. CSIC

8. 28006 Madrid

9. Instituto de Química Física Rocasolano

10. Departamento de Química y Física Teóricas

11. Instituto de Estructura de la Materia

12. Madrid 28006

Abstract

Vibrationally state selected predissociation lifetimes for the methyl radical in the 3pz Rydberg state have been measured by femtosecond velocity map imaging and the results explained by ab initio theoretical calculations.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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