Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)x]− (x = 0, 1, or 2)

Author:

Matuszek Karolina123,Chrobok Anna123,Coleman Fergal456,Seddon Kenneth R.456,Swadźba-Kwaśny Małgorzata456

Affiliation:

1. Department of Chemical Organic Technology and Petrochemistry

2. Silesian University of Technology

3. 44-100 Gliwice, Poland

4. QUILL

5. The Queen's University of Belfast

6. Belfast, United Kingdom

Abstract

The speciation of a family of inexpensive, easily prepared protonic ionic liquids, their physico-chemical properties and their performance as catalysts in the model esterification reaction have been correlated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference40 articles.

1. H. J. Arpe , Industrial Organic Chemistry , Wiley-VCH , Weinheim , 5th edn, 2010

2. Catalysis from A to Z: A Concise Encyclopedia 4th completely revised and enlarged edn. , ed. B. Cornils , W. A. Herrmann , C.-H. Wong and H.-W. Zanthoff , Wiley-VCH , Weinheim, Germany , 2013

3. M. Freemantle , An Introduction to Ionic Liquids , RSC Publications , Cambridge , UK, 2010

4. A. Stark and K. R.Seddon , “Ionic Liquids” , in Kirk-Othmer Encyclopaedia of Chemical Technology , ed. A. Seidel , John Wiley & Sons, Inc. , Hoboken, New Jersey , 5th edn., 2007 , vol. 26 , p. 836

5. 1-Methyl-3-ethylimidazolium hydrogen dichloride: synthesis and application to the study of protons in ambient-temperature chloroaluminate ionic liquids

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