Switching of the conformational flexibility of a diazacyclooctane-containing ladder polymer by coordination and elimination of a Lewis acid-Reference-Cited by-同舟云学术

Switching of the conformational flexibility of a diazacyclooctane-containing ladder polymer by coordination and elimination of a Lewis acid

Published:2020 Issue:2 Volume:11 Page:236-240
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Ishiwari Fumitaka¹²³⁴⁵^ORCID,Ofuchi Momoko¹²³⁴⁵,Inoue Keiki¹²³⁴⁵,Sei Yoshihisa⁶⁷³⁴⁵,Fukushima Takanori¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory for Chemistry and Life Science

2. Institute of Innovative Research

3. Tokyo Institute of Technology

4. Yokohama 226-8503

5. Japan

6. Suzukakedai Materials Analysis Division

7. Technical Department

Abstract

We report the first system of ladder polymers capable of interconversion between rigid and flexible conformations by coordination and elimination of a Lewis acid (BPh₂Cl) on diazacyclooctane units in the main chain.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Japan Prize Foundation

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/C9PY01104H

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5. Ladderphanes: A New Type of Duplex Polymers

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