Synthesis of amine-functionalized ZIF-8 with 3-amino-1,2,4-triazole by postsynthetic modification for efficient CO2-selective adsorbents and beyond

Author:

Cho Kie Yong12345ORCID,An Heseong6784,Do Xuan Huy12349,Choi Keunsu1011124,Yoon Ho Gyu1314154,Jeong Hae-Kwon5161718,Lee Jong Suk6784ORCID,Baek Kyung-Youl12349ORCID

Affiliation:

1. Materials Architecturing Research Center

2. Korea Institute of Science and Technology

3. Seoul 02792

4. Republic of Korea

5. Artie McFerrin Department of Chemical Engineering

6. Department of Chemical and Biomolecular Engineering

7. Sogang University

8. Seoul 121-742

9. Division of Nano & Information Technology

10. School of Energy and Chemical Engineering

11. Ulsan National Institute of Science and Technology

12. Ulsan 44919

13. Department of Materials Science and Engineering

14. Korea University

15. Seoul 02841

16. Texas A&M University

17. College Station

18. USA

Abstract

The facile tuning of the gate size and the chemical functionalization of zeolitic imidazolate framework-8 (ZIF-8) were achieved by the postsynthetic modification with 3-amino-1,2,4-triazole. The resulting amine functionalized ZIF-8 particles enabled CO2 selective adsorption and further chemical modifications.

Funder

National Research Council of Science and Technology

Ministry of Science, ICT and Future Planning

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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