Ru-catalyzed activation of free phenols in a one-step Suzuki–Miyaura cross-coupling under mechanochemical conditions

Author:

Mkrtchyan Satenik12ORCID,Jakubczyk Michał34ORCID,Sarfaraz Sehrish5,Ayub Khurshid5ORCID,Iaroshenko Viktor O.12678ORCID

Affiliation:

1. Department of Chemistry, Faculty of Natural Sciences, Matej Bel University, Tajovského 40, 97401, Banska Bystrica, Slovakia

2. University Centre for Research & Development, Chandigarh University, Mohali, Punjab, 140413, India

3. Institute of Inorganic Chemistry, Czech Academy of Sciences, Husinec-Řež č.p. 1001, 250 68 Husinec-Řež, Czech Republic

4. Laboratory of Molecular Assays and Imaging, Institute of Bioorganic Chemistry, Polish Academy of Sciences, Noskowskiego 12/14, 61-704, Poznań, Poland

5. Department of Chemistry, COMSATS University, Abbottabad Campus, Abbottabad, KPK, 22060, Pakistan

6. Department of Fiber and Polymer Technology, Division of Wood Chemistry and Pulp Technology, School of Chemistry, Biotechnology and Health, KTH Royal Institute of Technology, Teknikringen 56-58, SE-100 44 Stockholm, Sweden

7. Functional Materials Group, Gulf University for Science and Technology, Mubarak Al-Abdullah 32093, Kuwait

8. Centre of Research Impact and Outcome, Chitkara University Institute of Engineering and Technology, Chitkara University, Rajpura-140401, Punjab, India

Abstract

Activation of phenols by a Ru-catalyst allows for the resulting η5-phenoxo complex to selectively react with a variety of nucleophiles under mechanochemical conditions.

Funder

Knut och Alice Wallenbergs Stiftelse

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

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