Controlling conjugated polymer morphology by precise oxygen position in single-ether side chains

Author:

Durand Pablo1ORCID,Zeng Huiyan2,Jismy Badr1ORCID,Boyron Olivier3ORCID,Heinrich Benoît4ORCID,Herrmann Laurent2,Bardagot Olivier1ORCID,Moutsios Ioannis5ORCID,Mariasevskaia Alina V.6ORCID,Melnikov Alexey P.6ORCID,Ivanov Dimitri A.56ORCID,Brinkmann Martin2ORCID,Leclerc Nicolas1ORCID

Affiliation:

1. Université de Strasbourg, CNRS, ICPEES UMR 7515, 67087 Strasbourg, France

2. Université de Strasbourg, CNRS, ICS UPR 22, 67000 Strasbourg, France

3. Université de Lyon, CNRS, Laboratoire CP2M, UMR 5128, 69100 Villeurbanne, France

4. Université de Strasbourg, CNRS, IPCMS UMR 7504, F-67034 Strasbourg, France

5. Université de Mulhouse, CNRS, IS2M, UMR 7361, 15 Jean Starcky, Mulhouse 68057, France

6. Faculty of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, 119991 Moscow, Russia

Abstract

Single-ether side chains allow modulation of the oxygen position. The further the oxygen atom is from the backbone, the more crystalline the polymer. High doping levels and ordering lead to remarkable conductivities and thermoelectric performances.

Funder

Russian Science Foundation

Agence Nationale de la Recherche

European Synchrotron Radiation Facility

Publisher

Royal Society of Chemistry (RSC)

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