Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO2 under blue light-Reference-Cited by-同舟云学术

Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO2 under blue light

Published:2017 Issue:23 Volume:5 Page:11854-11863
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Logan Matthew W.¹²³⁴,Ayad Suliman¹⁵⁶⁴,Adamson Jeremy D.¹²³⁴,Dilbeck Tristan¹⁵⁶⁴,Hanson Kenneth¹⁵⁶⁴^ORCID,Uribe-Romo Fernando J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Central Florida

3. Orlando

4. USA

5. Florida State University

6. Tallahassee

Abstract

N-alkyl substitution–from methyl to heptyl–in isoreticular MIL-125-NH₂ MOFs induces a stepwise decrease in the optical bandgap, while increasing CO₂ photoreduction efficiencies.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TA/C7TA00437K

Reference54 articles.

1. The energy–climate challenge: Recent trends in CO2 emissions from fuel combustion

2. Photocatalytic Conversion of CO2into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects

3. Visible Light Photoreduction of CO2 Using CdSe/Pt/TiO2 Heterostructured Catalysts