Synthesis and reactivity of selenium functionalised allylidynes and propargylidynes
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
Abstract
The reactions of the trimethylsilylpropargylidyne [W(CCCSiMe3)(CO)2(Tp*)] (1: Tp* = hydrotris(dimethylpyrazolyl)borate) towards selenium centred reagents when treated with tetrabutylammonium fluoride (TBAF) were explored in order to prepare alkynylselenolato propargylidynes, e.g., [W(CCCSePh)(CO)2(Tp*)].
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02370K
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