Ring-opening mechanism of epoxides with alcohol and tertiary amines

Author:

Du Yongzhuang1,Xue Xiaoqiang12ORCID,Jiang Qimin13,Huang Wenyan13,Yang Hongjun13ORCID,Jiang Li13ORCID,Jiang Bibiao13ORCID,Komarneni Sridhar4ORCID

Affiliation:

1. Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou, Jiangsu 213164, People's Republic of China

2. Industrial College of Carbon Fiber and New Materials, School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou, Jiangsu 213000, People's Republic of China

3. Changzhou University Huaide College, Jingjiang 214500, People's Republic of China

4. Materials Research Institute and Department of Ecosystem Science and Management, 204 EEL, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

Abstract

The ring-opening reaction of epoxides with alcohol and tertiary amines was studied. NMR spectroscopy analysis confirmed that glycidol has a different ring-opening polymerization mechanism than other epoxides in the presence of tertiary amines.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Provincea

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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