Self-assembled octanuclear [Ni5Ln3] (Ln = Dy, Tb and Ho) complexes: synthesis, coordination induced ligand hydrolysis, structure and magnetism-Reference-Cited by-同舟云学术

Self-assembled octanuclear [Ni5Ln3] (Ln = Dy, Tb and Ho) complexes: synthesis, coordination induced ligand hydrolysis, structure and magnetism

Published:2020 Issue:23 Volume:49 Page:7968-7976
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhanja Avik¹²³⁴^ORCID,Moreno-Pineda Eufemio⁵⁶⁷⁸⁹,Herchel Radovan¹⁰¹¹¹²¹³¹⁴^ORCID,Wernsdorfer Wolfgang⁵⁶⁷⁸¹⁵^ORCID,Ray Debashis¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Kharagpur 721302

4. India

5. Institute of Nanotechnology (INT)

6. Karlsruhe Institute of Technology (KIT)

7. D-76344 Eggenstein-Leopoldshafen

8. Germany

9. Depto. de Química-Física

10. Department of Inorganic Chemistry

11. Faculty of Science

12. Palacky University

13. CZ-771 46 Olomouc

14. Czech Republic

15. Physikalisches Institut

Abstract

Octanuclear NiII5LnIII3 complexes obtained with ligand H₂L show ferromagnetic interactions for Ni₅Dy₃ and Ni₅Tb₃ while antiferromagnetic interactions for Ni₅Ho₃.

Funder

Department of Science and Technology, Ministry of Science and Technology

Alexander von Humboldt-Stiftung

European Research Council

Univerzita Palackého v Olomouci

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01675F

Reference56 articles.

1. A {CrIII2DyIII2} Single-Molecule Magnet: Enhancing the Blocking Temperature through 3d Magnetic Exchange

2. Synthesis, Structure, and Magnetic Properties of a Large Lanthanide–Transition-Metal Single-Molecule Magnet

3. Mn21Dy Cluster with a Record Magnetization Reversal Barrier for a Mixed 3d/4f Single-Molecule Magnet

4. Single-molecule magnetism in {CoIII2DyIII2}-amine-polyalcohol-acetylacetonate complexes: effects of ligand replacement at the DyIII sites on the dynamics of magnetic relaxation

5. Syntheses, Structures, and Magnetic Properties of a Family of Heterometallic Heptanuclear [Cu5Ln2] (Ln = Y(III), Lu(III), Dy(III), Ho(III), Er(III), and Yb(III)) Complexes: Observation of SMM behavior for the Dy(III) and Ho(III) Analogues

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