Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene-Reference-Cited by-同舟云学术

Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene

Published:2020 Issue:3 Volume:11 Page:862-869
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wilson Daniel W. N.¹²³⁴⁵^ORCID,Franco Mauricio P.¹²³⁴⁵^ORCID,Myers William K.¹²⁶⁷⁴^ORCID,McGrady John E.¹²³⁴⁵^ORCID,Goicoechea Jose M.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Oxford

3. Chemistry Research Laboratory

4. Oxford

5. UK

6. Centre for Advanced ESR

7. Inorganic Chemistry Laboratory

Abstract

We report on the (tert-butyl)isocyanide-catalysed isomersation of a phosphaethynolato-borane, [B]OCP, to its linkage isomer, a phosphaketenyl-borane, [B]PCO.

Funder

Engineering and Physical Sciences Research Council

University of Oxford

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05969E

Reference57 articles.

1. The Chemistry of the 2‐Phosphaethynolate Anion