A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation-Reference-Cited by-同舟云学术

A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

Published:2017 Issue:11 Volume:8 Page:7798-7806
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Ahmed Jasimuddin¹²³⁴,P Sreejyothi¹²³⁴,Vijaykumar Gonela¹²³⁴,Jose Anex¹²³⁴,Raj Manthan⁵⁶⁷⁴,Mandal Swadhin K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Sciences

2. Indian Institute of Science Education and Research Kolkata

3. Kolkata

4. India

5. Zakir Husain Delhi College

6. University of Delhi

7. Delhi-110002

Abstract

The first transition metal-free catalyzed direct C–H arylation of a variety of heteroarenes at room temperature has been reported using a phenalenyl-based radical without employing any photoactivation step.

Funder

SERB

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02661G

Reference52 articles.

1. Stable π-electron systems and new aromatic structures

2. The chemistry of the phenalenes

3. Magneto-Opto-Electronic Bistability in a Phenalenyl-Based Neutral Radical