Kinetic analysis to describe Co-operative redox enhancement effects exhibited by bimetallic Au–Pd systems in aerobic oxidation

Author:

Daniel Isaac T.1ORCID,Zhao Liang1ORCID,Bethell Donald1,Douthwaite Mark1,Pattisson Samuel1,Lewis Richard J.1ORCID,Akdim Ouardia1,Morgan David J.1ORCID,McIntosh Steven2ORCID,Hutchings Graham J.1ORCID

Affiliation:

1. Max Planck-Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT, Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK

2. Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, PA, USA

Abstract

Recent work has demonstrated that, for bimetallic Au–Pd systems, the rate of catalytic alcohol and formyl dehydrogenation (DH) is intrinsically linked to the rate of oxygen reduction (ORR) within the same system.

Funder

European Regional Development Fund

Wolfson Foundation

Chinese Government Scholarship

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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