Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication
Author:
Affiliation:
1. Institut für Chemie
2. Universität Rostock
3. 18059 Rostock
4. Germany
5. Abteilung Materialdesign
6. Leibniz-Institut für Katalyse e.V. an der Universität Rostock
Abstract
A bulky NPN-substituted dichlorostibane was reduced with KC8to afford a distibenium compound with a [Sb2]2+ion which can be regarded as a dimerization product of a stiba-phospha-diazanediyl singlet biradicaloid. The intermediate formation of this singlet stiba-phospha-diazanediyl was proven by trapping experiments.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02711J
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