Methyl substitution effects on the non-adiabatic dynamics of benzene: lifting three-state quasi-degeneracy at conical intersections-Reference-Cited by-同舟云学术

Methyl substitution effects on the non-adiabatic dynamics of benzene: lifting three-state quasi-degeneracy at conical intersections

Published:2020 Issue:5 Volume:22 Page:2814-2818
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Adachi Shunsuke¹²³⁴⁵^ORCID,Suzuki Toshinori¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University

4. Kyoto 606-8502

5. Japan

Abstract

Time-resolved photoelectron spectra of benzene and its methyl-derivatives (toluene and o-xylene) measured with a vacuum-UV laser clearly reveal both fast (A → B → C → D) and slow (B → C′ → D) relaxation channels from the S₂ state.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06164A

Reference24 articles.

1. Beyond Two-State Conical Intersections. Three-State Conical Intersections in Low Symmetry Molecules: the Allyl Radical

2. Three-State Conical Intersections in Nucleic Acid Bases

3. Competitive Decay at Two- and Three-State Conical Intersections in Excited-State Intramolecular Proton Transfer

4. Real-Time Observation of Nonadiabatic Bifurcation Dynamics at a Conical Intersection

5. Internal conversion in highly excited benzene and benzene dimer: femtosecond time-resolved photoelectron spectroscopy

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Molecular structures in the non-adiabatic relaxaiton processes of excited states of pentafluoropyridine;Acta Physica Sinica;2024

2. Intermolecular-Type Conical Intersections in Benzene Dimer;International Journal of Molecular Sciences;2023-02-02

3. Effect of conical intersection of benzene on non-adiabatic dynamics;Chinese Physics B;2022-07-01

4. Dynamics of Methyl Radical Formation Following 266 nm Dissociative Photoionization of Xylenes and Mesitylene;The Journal of Physical Chemistry A;2022-03-16

5. Benzene, Toluene, and Monosubstituted Derivatives: Diabatic Nature of the Oscillator Strengths of S1 ← S0 Transitions;The Journal of Physical Chemistry A;2021-06-16