Synthesis of 2-hydroxymalonic acid derivatives via tandem oxidation and rearrangement by photo organic catalysis-Reference-Cited by-同舟云学术

Synthesis of 2-hydroxymalonic acid derivatives via tandem oxidation and rearrangement by photo organic catalysis

Published:2016 Issue:48 Volume:6 Page:42596-42599
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Okada Akifumi¹²³,Nagasawa Yoshitomo¹²³,Yamaguchi Tomoaki¹²³,Yamaguchi Eiji¹²³,Tada Norihiro¹²³,Miura Tsuyoshi⁴⁵³,Itoh Akichika¹²³

Affiliation:

1. Gifu Pharmaceutical University 1-25-4

2. Gifu 501-1196

3. Japan

4. Tokyo University of Pharmacy and Life Sciences

5. Tokyo 192-0392

Abstract

This report describes a mild method for the direct transformation of β-oxoesters to the corresponding tartronic esters using singlet oxygen produced by a catalytic amount of methylene blue and visible light irradiation using fluorescent lamps.

Funder

Asahi Glass Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA07084A

Reference45 articles.

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4. New Mechanistic and Synthetic Aspects of Singlet Oxygen Chemistry

5. Regioselectivity in the Ene Reaction of Singlet Oxygen with Alkenes

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