Inverted energy gap law for the nonradiative decay in fluorescent floppy molecules: larger fluorescence quantum yields for smaller energy gaps-Reference-Cited by-同舟云学术

Inverted energy gap law for the nonradiative decay in fluorescent floppy molecules: larger fluorescence quantum yields for smaller energy gaps

Published:2019 Issue:12 Volume:6 Page:1948-1954
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Shi Junqing¹²³⁴⁵,Izquierdo Maria A.⁶⁷⁸⁹¹⁰,Oh Sangyoon¹¹¹²¹³¹⁴¹⁵,Park Soo Young¹¹¹²¹³¹⁴¹⁵^ORCID,Milián-Medina Begoña¹⁶¹⁷¹⁸¹⁹⁴^ORCID,Roca-Sanjuán Daniel¹⁰¹⁸²⁰⁴^ORCID,Gierschner Johannes¹²³⁴^ORCID

Affiliation:

1. Madrid Institute for Advanced Studies

2. IMDEA Nanoscience

3. 28049 Madrid

4. Spain

5. Xi'an Institute of Flexible Electronics

6. Zernike Institute for Advanced Materials

7. University of Groningen

8. 9747 AG Groningen

9. The Netherlands

10. Institute of Molecular Science

11. Center for Supramolecular Optoelectronic Materials

12. Department of Materials Science and Engineering

13. Seoul National University

14. Seoul 08826

15. Korea

16. Department for Physical Chemistry

17. Faculty of Chemistry

18. University of Valencia

19. 46100 Burjassot (Valencia)

20. 46980 Valencia

Abstract

The non-radiative decay of substituted dicyano-distyrylbenzenes in solution increase with the Franck–Condon energy, being opposite to the conventional energy gap law.

Funder

Ministerio de Economía y Competitividad

National Research Foundation of Korea

European Commission

China Scholarship Council

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00259F