N-Heterocyclic carbenes as chiral Brønsted base catalysts: a highly diastereo- and enantioselective 1,6-addition reaction-Reference-Cited by-同舟云学术

N-Heterocyclic carbenes as chiral Brønsted base catalysts: a highly diastereo- and enantioselective 1,6-addition reaction

Published:2018 Issue:30 Volume:9 Page:6446-6450
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Santra Surojit¹²³⁴,Porey Arka¹²³⁴,Jana Barun¹²³⁴,Guin Joyram¹²³⁴^ORCID

Affiliation:

1. Department of Organic Chemistry

2. Indian Association for the Cultivation of Science

3. Kolkata-700032

4. India

Abstract

Highly diastereo- and enantioselective 1,6-addition of β-keto amides to p-quinone methides catalyzed by N-heterocyclic carbenes via ion-pair interaction is developed.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02138D

Reference54 articles.

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2. Cooperative Catalysis and Activation with N-Heterocyclic Carbenes

3. Recent Advances in the N-Heterocyclic Carbene (NHC)-Organocatalyzed Stetter Reaction and Related Chemistry

4. Recent advances in employing homoenolates generated by N-heterocyclic carbene (NHC) catalysis in carbon–carbon bond-forming reactions

5. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

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