Creating capsules with cubanes

Author:

Kusumoto Sotaro12345,Kobayashi Fumiya12345,Ohtani Ryo12345ORCID,Zhang Yingjie67ORCID,Harrowfield Jack891011,Kim Yang12345ORCID,Hayami Shinya12345ORCID,Nakamura Masaaki12345

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Technology

3. Kumamoto University

4. Kumamoto 860-8555

5. Japan

6. Australian Nuclear Science and Technology Organisation

7. Australia

8. ISIS

9. Université de Strasbourg

10. 67083 Strasbourg

11. France

Abstract

A sextuply linked capsule incorporating two Ni(ii) cubane units is formed when Ni(ii) salts are reacted with N-aminoalkyl salicylamidato ligands in a 4 : 3 ratio in methanol.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference43 articles.

1. Anion encapsulation and dynamics in self-assembled coordination cages

2. P. W. N. Baxter , Metal Ion Directed Assembly of Complex Molecular Architectures and Nanostructures , in Comprehensive Supramolecular Chemistry , ed. J. L. Atwood , J. E. D. Davies , D. D. Macnicol and F. Vögtle , vol. 9 , ch. 5, pp. 165–211 (vol. eds. J.-P. Sauvage, M. W. Hosseini), Elsevier Science , Oxford, UK , 1996

3. Self-Assembly, Symmetry, and Molecular Architecture:  Coordination as the Motif in the Rational Design of Supramolecular Metallacyclic Polygons and Polyhedra

4. Metal-directed self-assembly of two- and three-dimensional synthetic receptors

5. Self-Assembly of [2]Catenanes Containing Metals in Their Backbones

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