Electrochemical Activation of Persulfate for Organic Pollution Control in Water

Author:

Liu Shuan12,Ding Haojie3,Zhang Jian1,Xu Qibin1,Duan Xiaodi4,Zhao Chun1

Affiliation:

1. National Centre for International Research of Low-carbon and Green Buildings, Chongqing University Chongqing 400045 P.R. China pureson@163.com pureson@cqu.edu.cn

2. College of Environmental Science and Engineering, Tongji University Shanghai P.R. China

3. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University Beijing P.R. China

4. Environmental Engineering and Science Program, Department of Chemical and Environmental Engineering (DChEE), University of Cincinnati Cincinnati United States

Abstract

Among various persulfate-activated processes, the electrochemical persulfate activation (E-PS) process has gained increasing interest in recent years. In this chapter, synergistic effects between electrolysis and persulfate are introduced. The operational factors (electrode type, current intensity, pH, water matrices, etc.), which could affect the removal efficiency of organic contaminants in the E-PS process, are discussed. Moreover, the organic contaminants’ degradation mechanisms as well as the generation paths of reactive oxygen species (ROS) in the E-PS process are summarized. At the end, future study trends on the E-PS process are proposed to give references for follow-up studies.

Publisher

The Royal Society of Chemistry

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