New Au(i)–Cu(i) heterometallic complexes: the role of bridging pyridazine ligands in the presence of unsupported metallophilic interactions

Author:

Donamaría Rocío12345,Fernández Eduardo J.12345,López-de-Luzuriaga José M.12345ORCID,Monge Miguel12345ORCID,Olmos M. Elena12345ORCID,Pascual David12345,Rodríguez-Castillo María12345

Affiliation:

1. Departamento de Química

2. Centro de Investigación en Síntesis Química (CISQ)

3. Universidad de La Rioja

4. Complejo Científico-Tecnoloǵico

5. 26006-Logroño

Abstract

The use of N-donor pyridazine ligands in different amounts in the reaction with a Au(i)/Cu(i) precursor allows the control of metallophilic interactions in the solid state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference49 articles.

1. C. Silvestru and A.Laguna, The Chemistry of Gold–Metal Bonds, Patai's Chemistry of Functional Groups, 2015, pp. 1–118

2. Optoelectronic Properties of Inorganic Compounds, ed. D. M. Roundhill and J. P. Fackler Jr., Plenum, New York, 1999, pp. 195–226

3. Gold–heterometal complexes. Evolution of a new class of luminescent materials

4. J. M. López-de-Luzuriaga , in Modern Supramolecular Gold Chemistry, ed. A. Laguna, Wiley-VCH, Weinheim, 2008, p. 347

5. 2-(Diphenylphosphino)-pyridine as an Ambidentate Ligand in Homo-and Hetero-binuclear Complexes of Copper, Silver, and Gold

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