Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ3-tmps)(CO)2NbE–R] (E = Si, Ge, Sn; tmps = MeSi(CH2PMe2)3; R = aryl)-Reference-Cited by-同舟云学术

Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ3-tmps)(CO)2NbE–R] (E = Si, Ge, Sn; tmps = MeSi(CH2PMe2)3; R = aryl)

Published:2017 Issue:9 Volume:8 Page:6290-6299
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Filippou Alexander C.¹²³⁴^ORCID,Hoffmann David¹²³⁴^ORCID,Schnakenburg Gregor¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Rheinische Friedrich-Wilhelms-Universität Bonn

3. 53121 Bonn

4. Germany

Abstract

A systematic, efficient route to the first heavier tetrylidyne complexes of niobium [(κ³-tmps)(CO)₂NbE–R] (E = Si–Sn; R = aryl) starting from the carbonyl niobate (NMe₄)[Nb(CO)₄(κ²-tmps)] is presented.

Funder

Jürgen Manchot Stiftung

Rheinische Friedrich-Wilhelms-Universität Bonn

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02708G

Reference98 articles.

1. Metal-Silicon Triple Bonds: The Molybdenum Silylidyne Complex [Cp(CO)2Mo≡Si-R]

2. Metal-Silicon Triple Bonds: Nucleophilic Addition and Redox Reactions of the Silylidyne Complex [Cp(CO)2MoSi-R]