17O solid state NMR as a valuable tool for deciphering reaction mechanisms in mechanochemistry: the case study on the 17O-enrichment of hydrated Ca-pyrophosphate biominerals

Author:

Goldberga Ieva1ORCID,Jensen Nicholai D.1,Combes Christèle2ORCID,Mentink-Vigier Frédéric3ORCID,Wang Xiaoling3ORCID,Hung Ivan3ORCID,Gan Zhehong3ORCID,Trébosc Julien4ORCID,Métro Thomas-Xavier5ORCID,Bonhomme Christian6ORCID,Gervais Christel6ORCID,Laurencin Danielle1ORCID

Affiliation:

1. ICGM, Université de Montpellier, CNRS, ENSCM, Montpellier, France

2. CIRIMAT, Université de Toulouse, CNRS, Toulouse INP – ENSIACET, Toulouse, France

3. National High Magnetic Field Laboratory (NHMFL), Tallahassee, Florida, USA

4. Université de Lille, CNRS, INRAE, Centrale Lille, Université d'Artois FR2638 – IMEC – Institut Michel Eugène Chevreul, 59000 Lille, France

5. IBMM, Université de Montpellier, CNRS, ENSCM, Montpellier, France

6. LCMCP, UMR 7574, Sorbonne Université, CNRS, Paris, France

Abstract

The possibility of enriching in 17O the water molecules within hydrated biominerals belonging to the Ca-pyrophosphate family was investigated, using liquid assisted grinding (LAG) in the presence of 17O-labelled water.

Funder

H2020 European Research Council

Agence Nationale de la Recherche

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Reference33 articles.

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