Doped metal clusters as bimetallic AuCo nanocatalysts: insights into structural dynamics and correlation with catalytic activity by in situ spectroscopy

Author:

Barrabés Noelia1ORCID,Ostolaza Jon12ORCID,Reindl Sarah1,Mähr Martin1,Schrenk Florian1ORCID,Drexler Hedda1,Rameshan Christoph1ORCID,Olszewski Wojciech3ORCID,Rupprechter Günther1ORCID

Affiliation:

1. Institute of Materials Chemistry, Technische Universität Wien, Getreidemarkt 9/165, 1060 Vienna, Austria

2. Department of Chemical Engineering and Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, UK

3. Faculty of Physics, University of Bialystok, ul. K. Ciolkowskiego 1L, 15-245 Bialystok, Poland

Abstract

Cobalt doping of Au25 nanoclusters led to an enhancement in the catalytic behaviour. The evolution of the doped Au clusters to nanoalloys with controlled surface sites was revealed by combined XAFS, DRIFTS and XPS studies.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Reference44 articles.

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4. Magic-Numbered Aun Clusters Protected by Glutathione Monolayers (n = 18, 21, 25, 28, 32, 39):  Isolation and Spectroscopic Characterization

5. Divide and Protect:  Capping Gold Nanoclusters with Molecular Gold−Thiolate Rings

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