Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M4L6 tetrahedral cages-Reference-Cited by-同舟云学术

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Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M4L6 tetrahedral cages

Published:2021 Issue:14 Volume:12 Page:5134-5142
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Scott Aaron J.¹²³⁴,Vallejo Julia¹²³⁴,Sarkar Arup⁵⁶⁷⁸,Smythe Lucy⁹¹⁰¹¹¹²¹³,Regincós Martí E.⁹¹⁰¹¹¹²¹³^ORCID,Nichol Gary S.¹²³⁴^ORCID,Klooster Wim T.¹⁴¹⁵¹⁶¹⁷¹⁸,Coles Simon J.¹⁴¹⁵¹⁶¹⁷¹⁸^ORCID,Murrie Mark⁹¹⁰¹¹¹²¹³^ORCID,Rajaraman Gopalan⁵⁶⁷⁸^ORCID,Piligkos Stergios⁵¹⁹²⁰²¹²²^ORCID,Lusby Paul J.¹²³⁴^ORCID,Brechin Euan K.¹²³⁴^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh

4. UK

5. Department of Chemistry

6. Indian Institute of Technology Bombay

7. Mumbai 400076

8. India

9. WestCHEM

10. School of Chemistry

11. University of Glasgow

12. University Avenue

13. Glasgow

14. UK National Crystallographic Service

15. Chemistry

16. Faculty of Natural and Environmental Sciences

17. University of Southampton

18. England SO17 1BJ

19. University of Copenhagen

20. Universitetsparken 5

21. 2100 Copenhagen

22. Denmark

Abstract

The tetrahedral [Ni^II₄L₆]⁸⁺ cage can reversibly bind paramagnetic MX₄^1/2− guests, inducing magnetic exchange interactions between host and guest.

Funder

Engineering and Physical Sciences Research Council

British Council

UK-India Education and Research Initiative

Villum Fonden

Diamond Light Source

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Industrial Research and Consultancy Centre

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00647A

Reference45 articles.

1. White Phosphorus Is Air-Stable Within a Self-Assembled Tetrahedral Capsule

2. A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length

3. Synergistic Noncovalent Catalysis Facilitates Base-Free Michael Addition

4. Stimuli-responsive Pd2L4metallosupramolecular cages: towards targeted cisplatin drug delivery

5. The “Complex-in-a-Complex” Cations [(acac)2M⊂Ru6(p-iPrC6H4Me)6(tpt)2(dhbq)3]6+: A Trojan Horse for Cancer Cells

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