Donor–acceptor random regioregular π-conjugated copolymers based on poly(3-hexylthiophene) with unsymmetrical monothienoisoindigo units

Author:

Uegaki Kaoru1234,Nakabayashi Kazuhiro5674,Yamamoto Shin-ichi1234,Koizumi Toshio1234ORCID,Hayashi Shotaro8910114ORCID

Affiliation:

1. Department of Applied Chemistry

2. National Defence Academy

3. Yokosuka

4. Japan

5. Graduate School of Organic Materials Science

6. Yamagata University

7. Yonezawa

8. Research Center for Molecular Design

9. School of Environmental Science and Engineering

10. Kochi University of Technology

11. Kami

Abstract

Donor–acceptor π-conjugated random copolymers based on regioregular poly(3-hexylthiophene) with unsymmetrical monothienoisoindigo moieties were obtained by direct arylation polycondensation.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference49 articles.

1. F.Livi , J. E.Carlé and E.Bundgaard , Thiophene in conducting polymers: synthesis of poly(thiophene)s and other conjugated polymers containing thiophenes, for application in polymer solar cells , in Thiophenes , ed. J. A. Joule , Springer International Publishing , Cham , 2015

2. Poly(3-hexylthiophene) (P3HT): fruit fly or outlier in organic solar cell research?

3. From a benzodiazaborole-based compound to donor–acceptor polymer via electropolymerization

4. Effects of molecular weight on the optical and electrochemical properties of EDOT-based π-conjugated polymers

5. Direct arylation polycondensation of β-unprotected chalcogen heteroles under phosphine-free conditions

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