Isosorbide bis(methyl carbonate) synthesis from isosorbide and dimethyl carbonate: the key role of dual basic–nucleophilic catalysts

Author:

Ochoa-Gómez José R.12345ORCID,Lorenzo-Ibarreta Leire12345ORCID,Diñeiro-García Cristina12345ORCID,Gómez-Jiménez-Aberasturi Olga12345ORCID

Affiliation:

1. TECNALIA

2. Basque Research and Technology Alliance (BRTA)

3. Parque Tecnológico de Alava

4. 01510 Miñano (Alava)

5. Spain

Abstract

Basic–nucleophilic nitrogenated organocatalysts catalyze the synthesis of isosorbide bis(methyl carbonate), with nucleophilicity having an influence twice as much as basicity on catalytic activity.

Funder

Bio Based Industries Joint Undertaking (JU) – Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference35 articles.

1. Isosorbide as a Renewable Platform chemical for Versatile Applications-Quo Vadis?

2. Synthesis of isosorbide: an overview of challenging reactions

3. J. R.Ochoa-Gómez and T.Roncal , in Production of Platform Chemicals from Renewable Resources , ed. Z. Fang , R. L. Smith Jr and X. Qi , Springer Book Series - Biofuels and Biorefineries, Singapore , 2017 , ch. 9, vol. 7 , pp. 265–310

4. A perspective on emerging polymer technologies for bisphenol-A replacement

5. VIPRISCAR: Validation of an industrial process to manufacture isosorbide bis(methyl carbonate) at pilot level . https://vipriscar.eu/

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