Effect of head group size on the photoswitching applications of azobenzene Disperse Red 1 analogues
Author:
Affiliation:
1. Department of Chemistry
2. McGill University
3. Montreal, Canada
4. Aalto University
5. Optics and Photonics Group
6. Department of Applied Physics
7. , Finland
Abstract
We investigate the effect of the increased molecular bulk in the ‘head’ group for a class of newly synthesized azobenzene chromophores and demonstrate that motifs with larger free-volume changes during isomerization drive photoinduced macromolecular phenomena.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/TC/C4TC00996G
Reference31 articles.
1. Photoisomerization of Disperse Red 1 Studied with Transient Absorption Spectroscopy and Quantum Chemical Calculations
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4. K. G. Yager and C. J.Barrett, Azobenzene Polymers for Photonic Applications, John Wiley & Sons Ltd, Boca Raton, 2009
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