Ultrafast dissociation of ammonia: Auger Doppler effect and redistribution of the internal energy

Author:

Travnikova Oksana1ORCID,Kukk Edwin2,Hosseini Farzad13ORCID,Granroth Sari2,Itälä Eero2,Marchenko Tatiana1ORCID,Guillemin Renaud1ORCID,Ismail Iyas1ORCID,Moussaoui Roba1,Journel Loïc1ORCID,Bozek John2,Püttner Ralph4ORCID,Krasnov Pavel56ORCID,Kimberg Victor56ORCID,Gel'mukhanov Faris567ORCID,Piancastelli Maria Novella18ORCID,Simon Marc1ORCID

Affiliation:

1. Sorbonne Université, CNRS, UMR 7614, Laboratoire de Chimie Physique-Matière et Rayonnement, F-75005 Paris, France

2. Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland

3. Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin, F-91192 Gif-sur-Yvette Cedex, France

4. Fachbereich Physik, Freie Universität Berlin, D-14195 Berlin, Germany

5. Department of Theoretical Chemistry and Biology, KTH Royal Institute of Technology, 10691 Stockholm, Sweden

6. International Research Center of Spectroscopy and Quantum Chemistry - IRC SQC, Siberian Federal University, 660041 Krasnoyarsk, Russia

7. Institute for Methods and Instrumentation in Synchrotron Radiation Research FG-ISRR, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, 12489 Berlin, Germany

8. Department of Physics and Astronomy, Uppsala University, SE-751 20 Uppsala, Sweden

Abstract

Vibrationally-resolved resonant Auger electron–photoion coincidence measurements allow observing the Auger–Doppler effect in ammonia following ultrafast dissociation. About 43% of the internal energy left in the system is transferred to vibrations.

Funder

Svenska Forskningsrådet Formas

VINNOVA

Agence Nationale de la Recherche

Vetenskapsrådet

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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