Synthesis of cyclohexanol and ethanol via the hydrogenation of cyclohexyl acetate with Cu2Znx/Al2O3 catalysts-Reference-Cited by-同舟云学术

Synthesis of cyclohexanol and ethanol via the hydrogenation of cyclohexyl acetate with Cu2Znx/Al2O3 catalysts

Published:2021 Issue:21 Volume:11 Page:7035-7046
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Qi Yuanyuan¹,Song Tongyang¹,Li Kefan¹,Wu Peng¹^ORCID,Zhu Zhirong²,Li Xiaohong¹^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, 3663 North Zhongshan Rd, Shanghai 200062, China

2. Department of Chemistry, Tongji University, 1239 Siping Road, Shanghai 200092, China

Abstract

The Cu2Zn1.25/Al2O3 catalyst exhibited 93.9% conversion and 97.2% selectivity to ethanol with 97.1% selectivity to cyclohexanol for the hydrogenation of cyclohexyl acetate due to the abundant weak acid sites and the highest ratio of Cu+/(Cu0 + Cu+).

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY01355F

Reference44 articles.

1. Mass transfer and solubility in autocatalytic oxidation of cyclohexane

2. Efficient Hydrolysis of Cyclohexyl Acetate to Cyclohexanol Catalyzed by Dual-SO3H-Functionalized Heteropolyacid-Based Solid Acids