The darkening of copper- or lead-based pigments explained by a structural modification of natural orpiment: a spectroscopic and electrochemical study
Author:
Affiliation:
1. Polychrome Artefact Laboratory
2. Royal Institute for Cultural Heritage
3. B-1000 Brussels
4. Belgium
5. AXES Research Group
6. University of Antwerp
7. B-2020 Antwerp
Abstract
A combined spectroscopic and electrochemical study is used to understand the mechanism by which natural orpiment darken copper- or lead-based pigments.
Funder
Federaal Wetenschapsbeleid
Publisher
Royal Society of Chemistry (RSC)
Subject
Spectroscopy,Analytical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/JA/C7JA00047B
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1. The darkening of zinc yellow: XANES speciation of chromium in artist's paints after light and chemical exposures
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3. Characterization of a Degraded Cadmium Yellow (CdS) Pigment in an Oil Painting by Means of Synchrotron Radiation Based X-ray Techniques
4. Combined use of Synchrotron Radiation Based Micro-X-ray Fluorescence, Micro-X-ray Diffraction, Micro-X-ray Absorption Near-Edge, and Micro-Fourier Transform Infrared Spectroscopies for Revealing an Alternative Degradation Pathway of the Pigment Cadmium Yellow in a Painting by Van Gogh
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