Polyphosphazenes for the Stille reaction: a new type of recyclable stannyl reagent
Author:
Affiliation:
1. IU CINQUIMA/Química Inorgánica
2. Universidad de Valladolid
3. 47071-Valladolid
4. Spain
5. Departamento de Química Orgánica e Inorgánica
6. IUQOEM
7. Universidad de Oviedo
8. 33006-Oviedo
Abstract
Random and block phosphazene copolymers with stannyl groups have been used as recyclable tin reagents in the Stille reaction. The block copolymer can be recycled without significant release of tin, but its efficiency decreased after three cycles, an effect related to the self-assembly of the polymer.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02670A
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