Synthesis ofN-methylated unsymmetric porphyrinoids with restrictedN-centered chirality from chlorophyll-a-Reference-Cited by-同舟云学术

Synthesis ofN-methylated unsymmetric porphyrinoids with restrictedN-centered chirality from chlorophyll-a

Published:2020 Issue:48 Volume:18 Page:9800-9804
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kawamoto Yuki¹²³⁴,Nagano Yasunobu¹²³⁴,Kitagawa Yuichi⁵⁶⁷⁸⁴^ORCID,Tamiaki Hitoshi¹²³⁴^ORCID

Affiliation:

1. Graduate School of Life Sciences

2. Ritsumeikan University

3. Kusatsu

4. Japan

5. Division of Materials Chemistry

6. Faculty of Engineering

7. Hokkaido University

8. Sapporo

Abstract

N-Centered chiral stereoisomers of regioselectivelyN-methylated chlorophyll-aderivatives with a cationic distorted π-skeleton were successfully separated.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB02146F

Reference23 articles.

1. Resolution of chiral nitrogen atoms in 1D helical coordination polymers

2. Catalytic Asymmetric Synthesis of N-Chiral Amine Oxides

3. N-Centered Chiral Self-Sorting and Supramolecular Helix of Tröger's Base-Based Dimeric Macrocycles in Crystalline State

4. Structural Isomerism and chirality of N -monosubstituted protoporphyrins

5. The cytochrome P-450 active site. Regiospecificity of prosthetic heme alkylation by olefins and acetylenes.

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