Covalent triazine framework/carbon nanotube hybrids enabling selective reduction of CO2 to CO at low overpotential

Author:

Laemont Andreas12345,Abednatanzi Sara12345ORCID,Derakshandeh Parviz Gohari12345ORCID,Verbruggen Florian67458ORCID,Fiset Erika67458ORCID,Qin Qing910111213,Van Daele Kevin141516178ORCID,Meledina Maria1819201321,Schmidt Johannes22232413,Oschatz Martin910111213ORCID,Van Der Voort Pascal12345ORCID,Rabaey Korneel67458ORCID,Antonietti Markus910111213ORCID,Breugelmans Tom141516178ORCID,Leus Karen12345ORCID

Affiliation:

1. COMOC – Center for Ordered Materials

2. Organometallics and Catalysis

3. Department of Chemistry

4. Ghent University

5. 9000 Ghent

6. CMET – Center for Microbial Ecology and Technology

7. Department of Biotechnology

8. Belgium

9. Max Planck Institute of Colloids and Interfaces

10. Colloid Chemistry

11. Research Campus Golm

12. 14476 Potsdam

13. Germany

14. ELCAT – Applied Electrochemistry & Catalysis

15. Faculty of Applied Engineering

16. University of Antwerp

17. 2610 Antwerp

18. RWTH Aachen University

19. Central Facility for Electron Microscopy

20. D-52074 Aachen

21. Forschungszentrum Jülich GmbH

22. Institut für Chemie − Funktionsmaterialien

23. Technische Universität Berlin

24. 10623 Berlin

Abstract

Nitrogen-rich covalent triazine frameworks (CTFs) were grown in situ onto surface-functionalized carbon nanotubes. These novel hybrid catalysts electrochemically reduce CO2 to CO with a faradaic efficiency up to 81% at an overpotential of 380 mV.

Funder

Bijzonder Onderzoeksfonds

Fonds Wetenschappelijk Onderzoek

H2020 European Institute of Innovation and Technology

Universiteit Gent

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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