Ruthenium(ii) arene complexes bearing simple dioxime ligands: effective catalysts for the one-pot transfer hydrogenation/N-methylation of nitroarenes with methanol

Author:

Colaiezzi Roberta1ORCID,Saviozzi Chiara23ORCID,di Nicola Nicola1,Zacchini Stefano4ORCID,Pampaloni Guido23ORCID,Crucianelli Marcello1ORCID,Marchetti Fabio23ORCID,Di Giuseppe Andrea1ORCID,Biancalana Lorenzo23ORCID

Affiliation:

1. Dipartimento di Scienze Fisiche e Chimiche, Università dell'Aquila, Via Vetoio, I-67100 L'Aquila, Italy

2. Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via G. Moruzzi 13, I-56124 Pisa, Italy

3. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC), Via Celso Ulpiani 27, I-70126 Bari, Italy

4. Dipartimento di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale del Risorgimento 4, I-40136 Bologna, Italy

Abstract

Ruthenium(ii) η6-arene complexes with easily-available dioxime ligands are efficient catalytic precursors for the selective reduction/N-methylation of aromatic nitrocompounds with methanol.

Funder

Università di Pisa

Università degli Studi dell'Aquila

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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