Bright aspects of defects and dark traits of dopants in the photoluminescence of Er2X2O7:Eu3+ (X = Ti and Zr) pyrochlore: an insight using EXAFS, positron annihilation and DFT

Author:

Gupta Santosh K.12345ORCID,Sudarshan K.12345ORCID,Jena Paramananda6785ORCID,Ghosh P. S.9245,Yadav A. K.102345ORCID,Jha S. N.111213514,Bhattacharyya D.111213510ORCID

Affiliation:

1. Radiochemistry Division

2. Bhabha Atomic Research Centre

3. Trombay

4. Mumbai-400085

5. India

6. School of Materials Science & Technology

7. Indian Institute of Technology (Banaras Hindu University)

8. Varanasi-221005

9. Glass and Advanced Materials Division

10. Atomic and Molecular Physics Division

11. Homi Bhabha National Institute

12. Anushaktinagar

13. Mumbai – 400094

14. Beamline Development & Application Section

Abstract

This work investigated the origin of blue PL in undoped and absence of Eu3+ red PL in the doped Er2X2O7 (X = Ti and Zr) pyrochlore using photon, positron and X-ray as spectroscopic probe and further complimenting with DFT.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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