Copper-assisted azide–alkyne cycloaddition chemistry as a tool for the production of emissive boron difluoride 3-cyanoformazanates
Author:
Affiliation:
1. Department of Chemistry
2. The University of Western Ontario
3. London
4. Canada
5. The Centre for Advanced Materials and Biomaterials Research (CAMBR)
6. Department of Oncology
7. London Regional Cancer Program
8. Department of Medical Imaging
Abstract
Emissive BF2 complexes of 3-cyanoformazanates produced using CuAAC chemistry are described. Highlights include ferrocene-substituted derivatives with ‘turn-on’ fluorescence upon oxidation and a water soluble derivative with application as a cell-imaging agent.
Funder
Natural Sciences and Engineering Research Council of Canada
Ministry of Research and Innovation
Canada Foundation for Innovation
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00640J
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